Why is recycled polyester considered a sustainable textile?

14 07 2009

plastic_bottles

Synthetic fibers are the most popular fibers in the world – it’s estimated that synthetics account for about 65% of world production versus 35% for natural fibers.[1] Most synthetic fibers (approximately 70%) are made from polyester, and the polyester most often used in textiles is polyethylene terephthalate (PET).   Used in a fabric, it’s most often referred to as “polyester” or “poly”.

The majority of the world’s PET production – about 60% – is used to make fibers for textiles; about 30% is used to make bottles.   It’s estimated that it takes about 104 million barrels of oil for PET production each year – that’s 70 million barrels just to produce the virgin polyester used in fabrics.[2] That means most polyester – 70 million barrels worth –  is manufactured specifically to be made into fibers, NOT bottles, as many people think.  Of the 30% of PET which is used to make bottles, only a tiny fraction is recycled into fibers.  But the idea of using recycled bottles – “diverting waste from landfills” – and turning it into fibers has caught the public’s imagination.

The reason recycled polyester (often written rPET) is considered a green option in textiles today is twofold, and the argument goes like this:

  1. energy needed to make the rPET is less than what was needed to make the virgin polyester in the first place, so we save energy.
  2. And  we’re keeping bottles and other plastics out of the landfills.

Let’s look at these arguments.

1) The energy needed to make the rPET is less than what is needed to make the virgin polyester, so we save energy:

It is true that recycling polyester uses less energy that what’s needed to produce virgin polyester.  Various studies all agree that it takes  from 33%  to 53% less energy[3].  If we use the higher estimate, 53%,  and take 53% of the total amount of energy needed to make virgin polyester (125 MJ per KG of ton fiber)[4], the amount of energy needed to produce recycled polyester in relation to other fibers is:

Embodied Energy used in production of various fibers:

energy use in MJ per KG of fiber:

hemp, organic

2

flax

10

hemp, conventional

12

cotton, organic, India

12

cotton, organic, USA

14

cotton,conventional

55

wool

63

rPET

66

Viscose

100

Polypropylene

115

Polyester

125

acrylic

175

Nylon

250

rPET is also cited as producing far fewer emissions to the air than does the production of  virgin polyester: again estimates vary, but Libolon’s website introducing its new RePET yarn put the estimate at 54.6% fewer CO2 emissions.  Apply that percentage to the data from the Stockholm Environment Institute[5], cited above:

KG of CO2 emissions per ton of spun fiber:

crop cultivation

fiber production

TOTAL

polyester USA

0

9.52

9.52

cotton, conventional, USA

4.2

1.7

5.89

rPET

5.19

hemp, conventional

1.9

2.15

4.1

cotton, organic, India

2

1.8

3.75

cotton, organic, USA

0.9

1.45

2.35

Despite the savings of both energy and emissions from the recycling of PET, the fact is that it is still more energy intensive to recycle PET into a  fiber than to use organically produced natural fibers – sometimes quite a bit more energy.

2) We’re diverting bottles and other plastics from the landfills.

That’s undeniably true,  because if you use bottles then they are diverted!

But the game gets a bit more complicated here because rPET is divided into “post consumer” PET and “post industrial” rPET:  post consumer means it comes from bottles; post industrial might be the unused packaging in a manufacturing plant, or other byproducts of manufacturing.  The “greenest” option has been touted to be the post consumer PET, and that has driven up demand for used bottles. Indeed, the demand for used bottles, from which recycled polyester fibre is made, is now outstripping supply in some areas and certain cynical suppliers are now buying NEW, unused bottles directly from bottle producing companies to make polyester textile fiber that can be called recycled.[6]

Using true post consumer waste means the bottles have to be cleaned (labels must be removed because labels often contain PVC) and sorted.  That’s almost always done in a low labor rate country since only human labor can be used.   Add to that the fact that the rate of bottle recycling is rather low – in the United States less than 6% of all waste plastic gets recycled [7].  The low recycling rate doesn’t mean we shouldn’t continue to try, but in the United States where it’s relatively easy to recycle a bottle and the population is relatively well educated in the intricacies of the various resin codes, doesn’t it make you wonder how successful we might be with recycling efforts in other parts of the world?

pet-recycling-graph-2 SOURCE: Container Recycling Institute

There are two types of recycling:  mechanical and chemical:

    • Mechanical recycling is accomplished by melting the plastic and re-extruding it to make yarns.  However, this can only be done  few times before the molecular structure breaks down and makes the yarn suitable only for the landfill[8] where it may never biodegrade, may biodegrade very slowly, or may add harmful materials to the environment as it breaks down (such as antimony).  William McDonough calls this  “downcycling”.
    • Chemical recycling means breaking the polymer into its molecular parts and reforming the molecule into a yarn of equal strength and beauty as the original.  The technology to separate out the different chemical building blocks (called depolymerization) so they can be reassembled (repolymerization) is very costly and almost nonexistent.

Most recycling is done mechanically (or as noted above, by actual people). Chemical recycling does create a new plastic which is of the same quality as the original,  but the process is very expensive and is almost never done, although Teijin has a new program which recycles PET fibers into new PET fibers.

The real problem with making recycled PET a staple of the fiber industry is this:  recycling, as most people think of it, is a myth.  Most people believe that plastics can be infinitely recycled  – creating new products of a value to equal the old bottles or other plastics which they dutifully put into recycling containers to be collected. The cold hard fact is that there is no such thing as recycling plastic, because it is not a closed loop.  None of the soda and milk bottles which are collected from your curbside are used to make new soda or milk bottles, because each time the plastic is heated it degenerates, so the subsequent iteration of the polymer is degraded and can’t meet food quality standards for soda and milk bottles.  The plastic must be used to make lower quality products.  The cycle goes something like this:

  • virgin PET can be made into soda or milk bottles,
  • which are collected and recycled into resins
    • which are appropriate to make into toys, carpet, filler for pillows, CD cases, plastic lumber products,  fibers or a million other products. But not new soda or milk bottles.
  • These second generation plastics can then be recycled a second time into park benches, carpet, speed bumps or other products with very low value.
  • The cycle is completed when the plastic is no longer stable enough to be used for any product, so it is sent to the landfill
    • where it is incinerated (sometimes for energy generation, which a good LCA will offset)  -
    • or where it will hold space for many years or maybe become part of the Great Pacific Garbage Patch![9]

And there is another consideration in recycling PET:  antimony, which is present in 80 – 85% of all virgin PET[10], is converted to antimony trioxide at high temperatures – such as are necessary during recycling, releasing this carcinogen from the polymer and making it available for intake into living systems.

Using recycled PET for fibers also creates some problems specific to the textile industry:

  • The base color of the recycled polyester chips vary from white to creamy yellow, making color consistency difficult to achieve, particularly for the pale shades.  Some dyers find it hard to get a white, so they’re using chlorine-based bleaches to whiten the base.
  • Inconsistency of dye uptake makes it difficult to get good batch-to-batch color consistency and this can lead to high levels of re-dyeing, another very high energy process.  Re-dyeing contributes to high levels of water, energy and chemical use.
  • Unsubstantiated reports claim that some recycled yarns take almost 30% more dye to achieve the same depth of shade as equivalent virgin polyesters.[11]
  • Another consideration is the introduction of PVC into the polymer from bottle labels and wrappers.
  • Many rPET fibers are used in forgiving constructions such as polar fleece, where the construction of the fabric hides slight yarn variations.  For fabrics such as satins, there are concerns over streaks and stripes.

Once the fibers are woven into fabrics, most fabrics are rendered non-recyclable  because:

  • the fabrics almost always have a chemical backing, lamination or other finish,
  • or they are blends of different synthetics (polyester and nylon, for example).

Either of these renders the fabric unsuitable for the mechanical method of recycling, which cannot separate out the various chemicals in order to produce the recycled yarn; the chemical method could  -   if we had the money and factories to do it.

One of the biggest obstacles to achieving McDonough’s Cradle-to-Cradle vision lies outside the designers’ ordinary scope of interest – in the recycling system itself. Although bottles, tins and newspapers are now routinely recycled, furniture and carpets still usually end up in landfill or incinerators, even if they have been designed to be  recycled [12] because project managers don’t take the time to separate out the various components of a demolition job, nor is collection of these components an easy thing to access.

Currently, the vision that most marketers has led us to believe, that of a closed loop, or cycle, in which the yarns never lose their value and recycle indefinitely is simply that – just a vision.  Few manufacturers, such as Designtex (with their line of EL fabrics designed to be used without backings) and Victor Innovatex (who has pioneered EcoIntelligent™ polyester made without antimony),  have taken the time, effort and money needed to accelerate the adoption of sustainable practices in the industry so we can one day have synthetic fabrics that are not only recycled, but recyclable.


[1] “New Approach of Synthetic Fibers Industry”, Textile Exchange,  http://www.teonline.com/articles/2009/01/new-approach-of-synthetic-fibe.html

[2] Polyester, Absolute Astronomy.com: http://www.absoluteastronomy.com/topics/Polyester and Pacific Institute, Energy Implications of Bottled Water, Gleick and Cooley, Feb 2009, http://www.pacinst.org/reports/bottled_water/index.htm)

[3] Website for Libolon’s RePET yarns:  http://www.libolon.com/eco.php

[4] Data compiled from:  “LCA: New Zealand Merino Wool Total Energy Use”, Barber and Pellow,                                                                       http://www.tech.plym.ac.uk/sme/mats324/mats324A9%20NFETE.htm and  “Ecological Footprint and Water

Analysis of Cotton, Hemp and Polyester”, by Cherrett et al, Stockholm Environment Institute

[5] “Ecological Footprint and Water Analysis of Cotton, Hemp and Polyester”, by Cherrett et al, Stockholm Environment Institute

[6] The Textile Dyer, “Concern over Recycled Polyester”, May 13, 2008,

[7] Watson, Tom, “Where can we put all those plastics?”, The Seattle Times, June 2, 2007

[8] William McDonough and Michael Braungart, “Transforming the Textile Industry”, green@work, May/June 2002.

[9] See www.greatgarbagepatch.org/

[10] Chemical Engineering Progress, May 2003

[11] “Reduce, re-use,re-dye?”,  Phil Patterson, Ecotextile News, August/September 2008

[12] “Taking Landfill out of the Loop”, Sarah Scott, Azure, 2006


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12 responses

14 07 2009
Harmony

You did it again! Educated me, brought complex information together in a comprehensive, cohesive (referenced) way. Thank you for this thoughtful and informative post.

14 07 2009
oecotextiles

Thanks so much for the morale boost, Harmony! Leigh Anne

16 07 2009
Mandy Behrens

Exceptional article! Harmony put it best. Cheers!

19 07 2009
Anna

Excellent article but I still have some questions. If all PET is made with antimony, what happens to the antimony? Is it treated from the waste water? Also, rPET causes antimony tri to be released. Where? Do these chemicals reside in the fabrics after they are completed?

The problem that I see is that rPET is being used in the commercial arena due to its supposed durability. What can designers use instead? Do cotton and hemp have enough rubs so that you are not reupholstering ever few years? Can part organic cotton and hemp be used with another eco friendly material to give it that durability? Wool can be tricky due to people’s sensitivities.

19 07 2009
oecotextiles

The antimony used in the production of the PET fibers becomes chemically bound to the PET polymer (although some is leached from the fibers during the high temperature dyeing process) so your PET fabric does contain antimony. The antimony that leaches from the fibers during the dyeing process is expelled with the wastewater into our rivers (unless the fabric is woven at a mill which treats its wastewater).
But what about the antimony that remains in the PET fabric? We do know that antimony leaches from PET bottles into the water or soda inside the bottles. But the US Agency for Toxic Substances and Disease Registry says that the antimony in fabric is very tightly bound and does not expose people to antimony. So if you want to take the government’s word for it, antimony in PET is not a problem for human health. (Toxics crusader William McDonough has been on antimony’s case for years, however, and takes a much less sanguine view of antimony.)
It’s just not a nice thing to be eating or drinking, and wearing it probably won’t hurt you, but the problem comes up during the production process – is it released into our environment? Recycling PET is a high temperature process, which creates wastewater tainted with antimony trioxide – and the dyeing process for recycled PET is problematic as I mentioned in last week’s post. Another problem occurs when the PET (recycled or virgin) is finally incinerated at the landfill – because then the antimony is released as a gas.
You’re right that designers are in love with polyesters because they’re so durable – and cheap (don’t forget cheap!). So they’re used a lot for public spaces. Abrasion results are a function not only of the fiber but also the construction of the fabric, and cotton and hemp can be designed to be very durable, but they will never achieve the same abrasion results that some polyesters have achieved – like 1,000,000 rubs. In the residential market, I would think most people wouldn’t want a fabric to last that long – I’ve noticed sofas which people leave on the streets with “free” signs on them, and never once did I notice that the sofa was suffering from fabric degredation! The “free” sofa just had to go because it was out of style, or stained, or something – I mean, have you even replaced a piece of furniture because the fabric had actually worn out? Hemp linens have been known to last for generations.
But synthetic fibers can do many things that make our lives easier, and in many ways they’re the true miracle fibers. I think there will always be a place for (organic) natural fibers, which are comfortable and soothing next to human skin. And they certainly have that cachet: doesn’t silk damask sound better than Ultrasuede? The versatile synthetics have a place in our textile set – but I think the current crop of synthetics must be changed so the toxic inputs are removed and the nonsustainable feedstock (oil) is replaced. I have great hope for the biobased polymer research going on, because the next generation of miracle fibers just might come from sustainable sources.

20 07 2009
Anna

I actually had 2 couches that were covered with a beautiful cotton print, which in five years with kids looked like it had seen much better days. Totally torn in many places.

The cost to reupholster and fabric is so expensive so I opted for a recycled poly fabric for duarability since I was so neverous about having to redo these couches again. I went with longevity. They told me no antimony was used in creating the fabric, but I am not sure they knew. At the time, there was not an organic cotton out there that had enough rubs. Would backing a cotton fabric helped with durability? Would it be much more expensive?

What are you thoughts on the Eco intelligent recycle polys?

20 07 2009
oecotextiles

Oh boy, I empathize with the part about your sofas taking a beating from kids. I have 3 boys, and we’ve had assorted dogs, so I totally know what you’re looking for in durability. Was the fabric construction on your sofa a sturdy one with a hefty weight? In any event, I can sure understand why you wanted to go with durability. For a bit of background: cotton as a fiber is much softer and of shorter lengths than either hemp or linen. Hemp is the most durable natural fiber, and researchers claim it has from 2 to 3x the tensile strength of cotton. Cotton is also a very short fiber (coming from the flower), averaging 0.79 -1.30 inches in length. Hemp’s average length is 8 inches, but can easily range up to 36” in length.

Backing the cotton fabric will help with durability. There are several backings you could use, each involving tradeoffs:
• A cotton knit backing (tradeoff: the cotton is probably not organic, and the adhesive used to glue the backing to the face should be nontoxic, and these are rare)
• A polyester backing: (tradeoff: this renders both the polyester and the cotton non-recyclable – really a moot point, but worth considering + issues surrounding use of plastics). Some would say why do this to a natural fiber, but which is better: a polyester backing on a natural fiber fabric or a polyester fabric (using more polyester)?
I don’t know about the cost to you for the backings; they would certainly increase the cost of the fabric!

Regarding the antimony in your fabric – if the fabric was made from polyester (which has the least toxic profile of all the synthetics) then the chances of it having antimony were pretty high, since 90% of the PET produced worldwide uses antimony as a catalyst in the production of the PET.

If they don’t use antimony as a catalyst they have to use something else, like Titanium. Not very many companies are taking the time and effort to change their manufacturing cycles, nor can they. It’s a huge investment to change the production process. There are very few companies that DO offer antimony free polyester, like Victor Innovatex which produces EcoIntelligent polyester, or Teijin in Japan. If I were buying a polyester I’d buy the antimony free polyester. But please remember that the EcoIntelligent polyesters are NOT recycled polyesters – they’re virgin polyester. So again you have to make a trade off – use the higher energy cost in producing the product, or have the toxins released into our ecosystem at some point during the product’s life. That’s why I think we need to give people better choices.

21 07 2009
Anna

Does antimony releases itself once it is on your couches. I was so careful not to use flame retardants, change the pads to natural latex, and was told that the fabric was antimony free.

About hemp, so which weight would be durable for rug rats? Why is some hemp you feel on sofas scatchy?

22 07 2009
oecotextiles

I think most of the research shows that it’s not a danger if antimony is in a fabric on our sofas, because the molecules are bound together chemically – it doesn’t become a free agent, as it were. The real danger is to our environment, thru release of the excess antimony in the mill effluent and again as antimony trioxide – which happens whenever the polymers are heated (as in polyester recycling, or during end of life burning at landfills). Another consideration that we think if worth noting: the literature is full of chemicals that the government and others told us were safe, only to be told further down the line that they weren’t. Look at lead: in 1971, the U.S. Surgeon General said that 60 mg of lead in a deciliter of blood was a safe level. In 1985 they reduced that to 25 mg, then in 1991 it was reduced to 10 mg and now we know that any detectable level of lead will shave off IQ points. Antimony causes cancer in mice and they know that exposure is cumulative- do you want it in your home, even if it IS bound in the polymer? What if they’re wrong?

It’s hard to give a specific weight for a hemp fabric that would be durable – if it looks to you like a sturdy fabric and it has a certain heft, then you should be good to go. If the fabric looks flimsy, or you can see thru it – then probably not.

Hemp has been given a bad rap because it IS a difficult fiber to work with. It can also be very coarse and scratchy, as you say. It takes an extra effort to make the hemp fibers soft, and until recently nobody was willing to spend the time and money on a fiber that many people wouldn’t consider buying because they equated it with rope. (By the way, hemp fibers soften and become more lustrous as they age, so old hemp fabrics are often very soft with a wonderful hand). Add to that the fact that you can’t even grow hemp in the United States, so research was spent on our best cash crop – cotton. And none of the mills in the U.S. could spin hemp, so it became the forgotten fiber.

It’s possible to find hemp fibers blended with other, softer fibers, such as cotton or viscose.

4 11 2009
Milan

I’m sorry if I’m bringing old topics back to life, but I have a question and I’m hoping you can help me with my dilemma. I’m looking for a skiing jacket and Patagonia is making great ones out of recycled polyester. Is it a smart thing to buy? If we suppose that they are using mechanical recycling method does that mean that the jackets they make have weaker fabric?
Thanks in advance,
Milan

4 11 2009
oecotextiles

Hi Milan: You know, just today I heard a great line: “Don’t expect to buy green products from brown companies”. That means that there are lots of companies jumping on the bandwagon – maybe they’ll add a couple of green products, or if they’re a fabric distributor with 60,000 skus they’ll introduce their new “green” collection of 48 skus. What percent of 60,000 is 48? (I actually used an online percentage calculator and got an answer that was so low as to be NA!). Do you think that company is seriously trying to make a difference? Well, Patagonia is NOT one of those brown companies. I’ve been impressed by Patagonia’s committment to our environment and the many steps they have taken for so long – in terms of research, new trials, new products, the whole works. There is a web site which gives an update on their Common Threads program (the recycling of garments) where you can read about some of the issues they’re grappeling with (http://www.thecleanestline.com/2009/03/closing-the-loop-a-report-on-patagonias-common-threads-garment-recycling-program.html). And though there are some unresolved issues about recycling polyester – and using plastics – I would support Patagonia because their heart’s in the right place and I trust them. And I would never think they’d sell a fabric for their jackets that has not been thoroughly tested. After all, they need to remain a vigorous company to fight the good fight!

5 11 2009
Milan

Thank you for your prompt response and let me express my support for your work, you’re doing an excellent work.

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